Volume I Part 3 (1/2)

But, besides this argument taken from what does not appear, the actual form in which those flinty ma.s.ses are found, demonstrates, _first_, That they have been introduced among those strata in a fluid state, by injection from some other place. 2_dly_, That they have been dispersed in a variety of ways among those strata, then deeply immersed at the bottom of the sea; and, _lastly_, That they have been there congealed from the state of fusion, and have remained in that situation, while those strata have been removed from the bottom of the ocean to the surface of the present land.

To describe those particular appearances would draw this paper beyond the bounds of an essay. We must, therefore, refer those who would inquire more minutely into the subject, to examine the chalk-countries of France and England, in which the flint is found variously formed; the land-hills interspersed among those chalk-countries, which have been also injected by melted flint; and the pudding-stone of England, which I have not seen in its natural situation. More particularly, I would recommend an examination of the insulated ma.s.ses of stone, found in the sand-hills by the city of Brussels; a stone which is formed by an injection of flint among sand, similar to that which, in a body of gravel, had formed the pudding-stone of England[7].

[Note 7: Accurate descriptions of those appearances, with drawings, would be, to natural history, a valuable acquisition.]

All these examples would require to be examined upon the spot, as a great part of the proof for the fusion of the flinty substance, arises, in my opinion, from the form in which those bodies are found, and the state of the surrounding parts. But there are specimens brought from many different places, which contain, in themselves, the most evident marks of this injection of the flinty substance in a fluid state. These are pieces of fossil wood, penetrated with a siliceous substance, which are brought from England, Germany, and Lochneagh in Ireland.

It appears from these specimens, that there has sometimes been a prior penetration of the body of wood, either with irony matter, or calcareous substance. Sometimes, again, which is the case with that of Lochneagh, there does not seem to have been any penetration of those two substances. The injected flint appears to have penetrated the body of this wood, immersed at the bottom of the sea, under an immense compression of water. This appears from the wood being penetrated partially, some parts not being penetrated at all.

Now, in the limits between those two parts, we have the most convincing proofs, that it had been flint in a simple fluid state which had penetrated the wood, and not in a state of solution.

_First_, Because, however little of the wood is left unpenetrated, the division is always distinct between the injected part and that which is not penetrated by the fluid flint. In this case, the flinty matter has proceeded a certain length, which is marked, and no farther; and, beyond this boundary, there is no partial impregnation, nor a gradation of the flintifying operation, as must have been the case if siliceous matter had been deposited from a solution. 2_dly_, The termination of the flinty impregnation has a.s.sumed such a form, precisely, as would naturally happen from a fluid flint penetrating that body.

In other specimens of this mineralising operation, fossil wood, penetrated, more or less, with ferruginous and calcareous substances, has been afterwards penetrated with a flinty substance. In this case, with whatever different substances the woody body shall be supposed to have been penetrated in a state of solution by water, the regular structure of the plant would still have remained, with its vacuities, variously filled with the petrifying substances, separated from the aqueous menstruum, and deposited in the vascular structure of the wood.

There cannot be a doubt with regard to the truth of this proposition; for, as it is, we frequently find parts of the consolidated wood, with the vascular structure remaining perfectly in its natural shape and situation; but if it had been by aqueous solution that the wood had been penetrated and consolidated, all the parts of that body would be found in the same natural shape and situation.

This, however, is far from being the case; for while, in some parts, the vascular structure is preserved entire, it is also evident, that, in general, the woody structure is variously broken and dissolved by the fusion and crystallization of the flint. There are so many and such various convincing examples of this, that, to attempt to describe them, would be to exceed the bounds prescribed for this dissertation; but such specimens are in my possession, ready for the inspection of any person who may desire to study the subject.

We may now proceed to consider sulphureous substances, with regard to their solubility in water, and to the part which these bodies have acted in consolidating the strata of the globe.

The sulphureous substances here meant to be considered, are substances not soluble in, water, so far as we know, but fusible by heat, and inflammable or combustible by means of heat and vital air. These substances are of two kinds; the one more simple, the other more compound.

The most simple kind is composed of two different substances, viz.

phlogiston, with certain specific substances; from which result, on the one hand, sulphur, and, on the other, proper coal and metals. The more compound sort, again, is oily matter, produced by vegetables, and forming bituminous bodies.

The _first_ of these is found naturally combined with almost all metallic substances, which are then said to be mineralised with sulphur.

Now, it is well known, that this mineralising operation is performed by means of heat or fusion; and there is no person skilled in chemistry that will pretend to say, this may be done by aqueous solution. The combination of iron and sulphur, for example, may easily be performed by fusion; but, by aqueous solution, this particular combination is again resolved, and forms an acido-metallic, that is, a vitriolic substance, after the phlogiston (by means of which it is insoluble in water) has been separated from the composition, by the a.s.sistance of vital air.

The variety of these sulphureo-metallic substances, in point of composition, is almost indefinite; but, unless they were all soluble in water, this could not have happened by the action of that solvent. If we shall allow any one of those bodies to have been formed by the fluidity of heat, they must all have been formed in the same manner; for there is such a chain of connection among those bodies in the mineral regions, that they must all have been composed, either, on the one hand, by aqueous solution, or, on the other, by means of heat and fusion.

Here, for example, are crystallised together in one ma.s.s, 1_st, Pyrites_, containing sulphur, iron, copper; 2_dly, Blend_, a composition of iron, sulphur, and calamine; 3_dly, Galena_, consisting of lead and sulphur; 4_thly, Marmor metallic.u.m_, being the terra ponderosa, saturated with the vitriolic acid; a substance insoluble in water; 5_thly, Fluor_, a saturation of calcareous earth, with a peculiar acid, called the _acid of spar_, also insoluble in water; 6_thly, Calcareous spar_, of different kinds, being calcareous earth saturated with fixed air, and something besides, which forms a variety in this substance; _lastly, Siliceous substance_, or _Quartz crystals_. All these bodies, each possessing its proper shape, are mixed in such a manner as it would be endless to describe, but which may be expressed in general by saying, that they are mutually contained in, and contain each other.

Unless, therefore; every one of these different substances may be dissolved in water, and crystallised from it, it is in vain to look for the explanation of these appearances in the operations of nature, by the means of aqueous solution.

On the other hand, heat being capable of rendering all these substances fluid, they may be, with the greatest simplicity, transported from one place to another; and they may be made to concrete altogether at the same time, and distinctly separate in any place. Hence, for the explanation of those natural appearances, which are so general, no further conditions are required, than the supposition of a sufficient intensity of subterraneous fire or heat, and a sufficient degree of compression upon those bodies, which are to be subjected to that violent heat, without calcination or change. But, so far as this supposition is not gratuitous, the appearances of nature will be thus explained.

I shall only mention one specimen, which must appear most decisive of the question. It is, I believe, from an Hungarian mine. In this specimen, petro-silex, pyrites, and cinnabar, are so mixed together, and crystallised upon each other, that it is impossible to conceive any one of those bodies to have had its fluidity and concretion from a cause which had not affected the other two. Now, let those who would deny the fusion of this siliceous body explain how water could dissolve these three different bodies, and deposit them in their present shape. If, on the contrary, they have not the least shadow of reason for such a gratuitous supposition, the present argument must be admitted in its full force.

Sulphur and metals are commonly found combined in the mineral regions.

But this rule is not universal; for they are also frequently in a separate state. There is not, perhaps, a metal, among the great number which are now discovered, that may not be found native, as they are called, or in their metallic state.

Metallic substances are also thus found in some proportion to the disposition of the particular metals, to resist the mineralising operations, and to their facility of being metallised by fire and fusion. Gold, which refuses to be mineralised with sulphur, is found generally in its native state. Iron, again, which is so easily mineralised and scorified, is seldom found in its malleable state. The other metals are all found more or less mineralised, though some of them but rarely in the native state.

Besides being found with circ.u.mstances thus corresponding to the natural facility, or to the impediments attending the metallization of those different calces, the native metals are also found in such a shape, and with such marks, as can only agree with the fusion of those bodies; that is to say, those appearances are perfectly irreconcilable with any manner of solution and precipitation.

For the truth of this a.s.sertion, among a thousand other examples, I appeal to that famous ma.s.s of native iron discovered by Mr Pallas in Siberia. This ma.s.s being so well known to all the mineralists of Europe, any comment upon its shape and structure will be unnecessary[8].

[Note 8: Since this Dissertation was written, M. de la Peyrouse has discovered a native manganese. The circ.u.mstances of this mineral are so well adapted for ill.u.s.trating the present doctrine, and so well related by M. de la Peyrouse, that I should be wanting to the interest of mineral knowledge, were I not to give here that part of his Memoir.