Volume III Part 13 (1/2)
As the century closed, half the philosophic world was speculating as to whether ”galvanic influence” were a new imponderable, or only a form of electricity; and the other half was eagerly seeking to discover what new marvels the battery might reveal. The least imaginative man could see that here was an invention that would be epoch-making, but the most visionary dreamer could not even vaguely adumbrate the real measure of its importance.
It was evident at once that almost any form of galvanic battery, despite imperfections, was a more satisfactory instrument for generating electricity than the frictional machine hitherto in use, the advantage lying in the fact that the current from the galvanic battery could be controlled practically at will, and that the apparatus itself was inexpensive and required comparatively little attention. These advantages were soon made apparent by the practical application of the electric current in several fields.
It will be recalled that despite the energetic endeavors of such philosophers as Watson, Franklin, Galvani, and many others, the field of practical application of electricity was very limited at the close of the eighteenth century. The lightning-rod had come into general use, to be sure, and its value as an invention can hardly be overestimated. But while it was the result of extensive electrical discoveries, and is a most practical instrument, it can hardly be called one that puts electricity to practical use, but simply acts as a means of warding off the evil effects of a natural manifestation of electricity. The invention, however, had all the effects of a mechanism which turned electricity to practical account. But with the advent of the new kind of electricity the age of practical application began.
DAVY AND ELECTRIC LIGHT
Volta's announcement of his pile was scarcely two months old when two Englishmen, Messrs. Nicholson and Carlisle, made the discovery that the current from the galvanic battery had a decided effect upon certain chemicals, among other things decomposing water into its elements, hydrogen and oxygen. On May 7, 1800, these investigators arranged the ends of two bra.s.s wires connected with the poles of a voltaic pile, composed of alternate silver and zinc plates, so that the current coming from the pile was discharged through a small quant.i.ty of ”New River water.” ”A fine stream of minute bubbles immediately began to flow from the point of the lower wire in the tube which communicated with the silver,” wrote Nicholson, ”and the opposite point of the upper wire became tarnished, first deep orange and then black....” The product of gas during two hours and a half was two-thirtieths of a cubic inch.
”It was then mixed with an equal quant.i.ty of common air,” continues Nicholson, ”and exploded by the application of a lighted waxen thread.”
This demonstration was the beginning of the very important science of electro-chemistry.
The importance of this discovery was at once recognized by Sir Humphry Davy, who began experimenting immediately in this new field. He constructed a series of batteries in various combinations, with which he attacked the ”fixed alkalies,” the composition of which was then unknown. Very shortly he was able to decompose potash into bright metallic globules, resembling quicksilver. This new substance he named ”pota.s.sium.” Then in rapid succession the elementary substances sodium, calcium, strontium, and magnesium were isolated.
It was soon discovered, also, that the new electricity, like the old, possessed heating power under certain conditions, even to the fusing of pieces of wire. This observation was probably first made by Frommsdorff, but it was elaborated by Davy, who constructed a battery of two thousand cells with which he produced a bright light from points of carbon--the prototype of the modern arc lamp. He made this demonstration before the members of the Royal Inst.i.tution in 1810. But the practical utility of such a light for illuminating purposes was still a thing of the future.
The expense of constructing and maintaining such an elaborate battery, and the rapid internal destruction of its plates, together with the constant polarization, rendered its use in practical illumination out of the question. It was not until another method of generating electricity was discovered that Davy's demonstration could be turned to practical account.
In Davy's own account of his experiment he says:
”When pieces of charcoal about an inch long and one-sixth of an inch in diameter were brought near each other (within the thirtieth or fortieth of an inch), a bright spark was produced, and more than half the volume of the charcoal became ignited to whiteness; and, by withdrawing the points from each other, a constant discharge took place through the heated air, in a s.p.a.ce equal to at least four inches, producing a most brilliant ascending arch of light, broad and conical in form in the middle. When any substance was introduced into this arch, it instantly became ignited; platina melted as readily in it as wax in a common candle; quartz, the sapphire, magnesia, lime, all entered into fusion; fragments of diamond and points of charcoal and plumbago seemed to evaporate in it, even when the connection was made in the receiver of an air-pump; but there was no evidence of their having previously undergone fusion. When the communication between the points positively and negatively electrified was made in the air rarefied in the receiver of the air-pump, the distance at which the discharge took place increased as the exhaustion was made; and when the atmosphere in the vessel supported only one-fourth of an inch of mercury in the barometrical gauge, the sparks pa.s.sed through a s.p.a.ce of nearly half an inch; and, by withdrawing the points from each other, the discharge was made through six or seven inches, producing a most brilliant coruscation of purple light; the charcoal became intensely ignited, and some platina wire attached to it fused with brilliant scintillations and fell in large globules upon the plate of the pump. All the phenomena of chemical decomposition were produced with intense rapidity by this combination.”(1)
But this experiment demonstrated another thing besides the possibility of producing electric light and chemical decomposition, this being the heating power capable of being produced by the electric current. Thus Davy's experiment of fusing substances laid the foundation of the modern electric furnaces, which are of paramount importance in several great commercial industries.
While some of the results obtained with Davy's batteries were practically as satisfactory as could be obtained with modern cell batteries, the batteries themselves were anything but satisfactory. They were expensive, required constant care and attention, and, what was more important from an experimental standpoint at least, were not constant in their action except for a very limited period of time, the current soon ”running down.” Numerous experimenters, therefore, set about devising a satisfactory battery, and when, in 1836, John Frederick Daniell produced the cell that bears his name, his invention was epoch-making in the history of electrical progress. The Royal Society considered it of sufficient importance to bestow the Copley medal upon the inventor, whose device is the direct parent of all modern galvanic cells. From the time of the advent of the Daniell cell experiments in electricity were rendered comparatively easy. In the mean while, however, another great discovery was made.
ELECTRICITY AND MAGNETISM
For many years there had been a growing suspicion, amounting in many instances to belief in the close relations.h.i.+p existing between electricity and magnetism. Before the winter of 1815, however, it was a belief that was surmised but not demonstrated. But in that year it occurred to Jean Christian Oersted, of Denmark, to pa.s.s a current of electricity through a wire held parallel with, but not quite touching, a suspended magnetic needle. The needle was instantly deflected and swung out of its position.
”The first experiments in connection with the subject which I am undertaking to explain,” wrote Oersted, ”were made during the course of lectures which I held last winter on electricity and magnetism. From those experiments it appeared that the magnetic needle could be moved from its position by means of a galvanic battery--one with a closed galvanic circuit. Since, however, those experiments were made with an apparatus of small power, I undertook to repeat and increase them with a large galvanic battery.
”Let us suppose that the two opposite ends of the galvanic apparatus are joined by a metal wire. This I shall always call the conductor for the sake of brevity. Place a rectilinear piece of this conductor in a horizontal position over an ordinary magnetic needle so that it is parallel to it. The magnetic needle will be set in motion and will deviate towards the west under that part of the conductor which comes from the negative pole of the galvanic battery. If the wire is not more than four-fifths of an inch distant from the middle of this needle, this deviation will be about forty-five degrees. At a greater distance the angle of deviation becomes less. Moreover, the deviation varies according to the strength of the battery. The conductor can be moved towards the east or west, so long as it remains parallel to the needle, without producing any other result than to make the deviation smaller.
”The conductor can consist of several combined wires or metal coils. The nature of the metal does not alter the result except, perhaps, to make it greater or less. We have used wires of platinum, gold, silver, bra.s.s, and iron, and coils of lead, tin, and quicksilver with the same result.
If the conductor is interrupted by water, all effect is not cut off, unless the stretch of water is several inches long.
”The conductor works on the magnetic needle through gla.s.s, metals, wood, water, and resin, through clay vessels and through stone, for when we placed a gla.s.s plate, a metal plate, or a board between the conductor and the needle the effect was not cut off; even the three together seemed hardly to weaken the effect, and the same was the case with an earthen vessel, even when it was full of water. Our experiments also demonstrated that the said effects were not altered when we used a magnetic needle which was in a bra.s.s case full of water.
”When the conductor is placed in a horizontal plane under the magnetic needle all the effects we have described take place in precisely the same way, but in the opposite direction to what took place when the conductor was in a horizontal plane above the needle.
”If the conductor is moved in a horizontal plane so that it gradually makes ever-increasing angles with the magnetic meridian, the deviation of the magnetic needle from the magnetic meridian is increased when the wire is turned towards the place of the needle; it decreases, on the other hand, when it is turned away from that place.
”A needle of bra.s.s which is hung in the same way as the magnetic needle is not set in motion by the influence of the conductor. A needle of gla.s.s or rubber likewise remains static under similar experiments. Hence the electrical conductor affects only the magnetic parts of a substance.
That the electrical current is not confined to the conducting wire, but is comparatively widely diffused in the surrounding s.p.a.ce, is sufficiently demonstrated from the foregoing observations.”(2)