Part 4 (1/2)
Dr. Young carried two papers to Philadelphia. The first article treated of ”Experiments and Observations relating to the a.n.a.lysis of Atmospherical Air,” and the second ”Further Experiments relating to the Generation of Air from Water.” They filled 20 quarto pages of Volume 4 of the Transactions of the American Philosophical Society. On reading them the thought lingers that these are the first contributions of the eminent philosopher from his American home. Hence, without reference to their value, they are precious. They represent the results of inquiries performed under unusual surroundings. It is very probable that Priestley's English correspondents desired him to concentrate his efforts upon experimental science. They were indeed pleased to be informed of his Church History, and his vital interest in religion, but they cherished the hope that science would in largest measure displace these literary endeavors. Priestley himself never admitted this, but must have penetrated their designs, and, recognizing the point of their urging, worked at much disadvantage to get the results presented in these two pioneer studies. Present day students would grow impatient in their perusal, because of the persistent emphasis placed on phlogiston, dephlogisticated air, phlogisticated air, and so forth. In the very first paper, the opening lines show this:
It is an essential part of the antiphlogistic theory, that in all the cases of what I have called _phlogistication_ of _air_, there is simply an absorption of the dephlogisticated air, or, as the advocates of that theory term it, the oxygen contained in it, leaving the _phlogisticated_ part, which they call _azote_, as it originally existed in the atmosphere. Also, according to this system, _azote_ is a simple substance, at least not hitherto a.n.a.lyzed into any other.
No matter how deeply one venerates Priestley, or how great honor is ascribed to him, the question continues why the simpler French view was not adopted by this honest student. Further, as an ardent admirer one asks why should Priestley pen the next sentence:
They, therefore, suppose that there is a determinate proportion between the quant.i.ties of oxygen, and azote in every portion of atmospherical air, and that all that has. .h.i.therto been done has been to separate them from one another. This proportion they state to be 27 parts of oxygen and 73 parts of azote, in 100 of atmospherical air.
Priestley knew that there was a ”determinate proportion.” He was not, however, influenced by quant.i.tative data.
Sir Oliver Lodge said[4]--
Priestley's experiments were admirable, but his perception of their theoretical relations was entirely inadequate and, as we now think, quite erroneous.... In theory he had no instinct for guessing right ... he may almost be said to have had a predilection for the wrong end.
At present the French thought is so evident that it seems incomprehensible that Priestley failed to grasp it, for he continues--
In every case of the diminution of atmospherical air in which this is the result, there appears to me to be something emitted from the substance, which the antiphlogistians suppose to act by simple absorption, and therefore that it is more probable that there is some substance, and the same that has been called _philogiston_, or the _principle of inflammability_ ... emitted, and that this phlogiston uniting with part of the dephlogisticated air forms with it part of the phlogisticated air, which is found after the process.
Subsequently (1798), he advised the Society that he had executed other experiments which corroborated those outlined in his first two papers, adding--
Had the publication of your _Transactions_ been more frequent, I should with much pleasure have submitted to the Society a full account of these and other experiments which appear to me to prove, that metals are compound substances, and that water has not yet been decomposed by any process that we are acquainted with.
Still, however, I would not be very positive, as the contrary is maintained by almost all the chemists of the age....
And thus he proceeds, ever doing interesting things, but blind to the patent results because he had phlogiston constantly before him. He looked everywhere for it, followed it blindly, and consequently overlooked the facts regarded as most significant by his opponents, which in the end led them to correct conclusions.
The experimental results in the second paper also admit of an interpretation quite the opposite of that deduced by Priestley. He confidently maintained that air was invariably generated from water, because he discovered it and liberated it from water which he was certain did not contain it in solution. He was conscientious in his inferences. Deeply did his friends deplore his inability to see more than a single interpretation of his results!
The papers were read before the American Philosophical Society on the 19th of February, 1796. Their author as they appear in print, is the Rev. Dr. J. Priestley. It is doubtful whether he affixed this signature.
More probable is it that the Secretary of the Society was responsible, and, because he thought of Priestley in the role of a Reverend gentleman rather than as a scientific investigator.
Here, perhaps, it may be mentioned that the first, the very first communication from Priestley's pen to the venerable Philosophical Society, was read in 1784. It was presented by a friend--a Mr. W.
Vaughan, whose family in England were always the staunchest of Priestley's supporters. And it is not too much to a.s.sume that it was the same influence which one year later (1785) brought about Priestley's election to members.h.i.+p in the Society, for he was one of ”28 new members” chosen in January of that year.
There are evidences of marked friendliness to Priestley all about the Hall of the Society, for example his profile in Plaster of Paris, ”particularly valuable for the resemblance” to the Doctor, which was presented in 1791; a second ”profile in black leather” given by Robert Patterson, a President of the Society, and an oil portrait of him from Mrs. Dr. Caspar Wistar.
His appearance in person, when for the first time he sat among his colleagues of the Society, was on the evening of February 19, 1796--the night upon which the two papers, commented upon in the last few paragraphs were presented, although he probably did not read them himself, this being done by a friend or by the secretary. Sixteen members were present. Among these were some whose names have become familiar elsewhere, such as Barton, Woodhouse and others. Today, the presence in the same old Hall of a renowned scientist, from beyond the seas, would literally attract crowds. Then it was not the fas.h.i.+on. But probably he had come unannounced and unheralded. Further, he was speaking at other hours on other topics in the city.
It is not recorded that he spoke before the philosophers. Perhaps he quietly absorbed their remarks and studied them, although he no doubt was agreeably aroused when Mr. Peale presented
to the Society a young son of four months and four days old, being the first child born in the Philosophical Hall, and requested that the Society would give him a name. On which the Society unanimously agreed that, after the name of the chief founder and late President of the Society, he should be called Franklin.
In antic.i.p.ation of any later allusion to Priestley's sojourn in Philadelphia be it observed that he attended meetings of the American Philosophical Society three times in 1796, twice in 1797, three times in 1801 and once in 1803, and that on February 3rd, 1797, he was chosen to deliver the annual oration before the Society, but the Committee reported that
they waited on Dr. Priestley last Monday afternoon, who received the information with great politeness, but declined accepting of the appointment.
This lengthy digression must now be interrupted. It has gone almost too far, yet it was necessary in order that an account of the early experimental contributions of the exile might be introduced chronologically. As already remarked, Americans are most deeply interested in everything Priestley did during his life in this country and particularly in his scientific activities.
On resuming the story of the routine at Northumberland in the closing months of the year 1795, there comes the cry from an agonized heart,--
We have lost poor Harry!